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AZ 4562 Photoresist - 3.785 l

AZ® 4562 is a thick positive resist with optimized adhesion for wet etching and plating.

Product information "AZ 4562 Photoresist - 3.785 l"

AZ® 4562

Thick Resists with Optimized Adhesion

 

General Information

The AZ® 4500 series (AZ® 4533 and AZ® 4562) are positive thick resists with optimized adhesion for common wet etching and plating processes. The AZ® 4500 series follows the AZ® 1500 series in the attainable and processable resist film thickness range. AZ® 4533 (3.3 µm resist film thickness at 4000 rpm) and AZ® 4562 (6.2 µm) have a lower photoinitiator con¬centration compared to thin resists. This makes it possible to process thick resist films over 10 µm without N2 bubble formation, but at the expense of a significantly lower development rate. A resist film thicknes up to 30 µm can be achieved by single-coating with adjusted spin profiles (short spin times at medium spin speed). Higher layer thicknesses can be achieved by multiple coating. Higher film thickness attainable with multiple coating.

Please note: Resist Film Thicknesses > 30 µm Generally, the AZ® 4562 can be coated and processed up to 30 µm and beyond. However, softbake, rehydration, exposure and development become very time-consuming in this thickness range. Additionally, even the rather transparent AZ® 4562 photoresist may form N2-bubbles during exposure when applied too thick. Therefore, for resist film thicknesses > 20 µm, we strongly recommend the chemically amplified AZ® 40XT.

Product Properties
  • Optimized resist adhesion to all common substrate materials
  • Broad process parameter window for stable and reproducible litho-processes
  • Compatible with all common developers (KOH- or TMAH-based)
  • Compatible with all common strippers (e.g. with AZ® 100 Remover, organic solvents, or aqueous alkaline)
  • g-, h- and i-line sensitive (approx. 320 - 440 nm)
  • Resist film thickness range approx. 5 - 30 µm
Developers

If metal ion containing developers can be used the KOH-based AZ® 400K in a 1:4 dilution or the finish diluted version AZ® 400K 1:4 (for higher resist film thicknesses 1:3.5 - 1:3 diluted possible) is a suited developer. If metal ion free developers have to be used, we recommend the TMAH-based AZ® 2026 MIF developer (undiluted).

Removers

For non cross-linked resist films the AZ® 100 Remover, DMSO or other common organic solvents can be used as stripper. If the resist film is cross-linked (e.g. by high temperature steps > 140°C, during plasma processes such as dry etching, or during ion implantation), we recommend the NMP-free TechniStrip P1316 as remover. AZ® 920 Remover can be a good choice as well, in case of harsh treated, hard to remove resist residuals.

Thinning/ Edge Bead Removal

We recommend for thinning and edge bead removal AZ® EBR Solvent.

Further Information

MSDS:
Safety Data Sheet AZ® 4562 Photoresist english
Sicherheitsdatenblatt AZ® 4562 Fotolack german

TDS:
Technical Data Sheet AZ® 4562 Photoresist english

Application Notes:
Further Information about Photoresist Processing

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Developer

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Remover

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DMSO - 2.50 l - ULSI
MDMU1025
DMSO Dimethyl Sulfoxide   General Information Due to its low vapour pressure and its water solubility, DMSO is an excellent stripper for resists respectively Lift-off media and is a non-toxic substitute for the NMP, which has been classified as toxic since a while. The optional addition of Cyclopentanone or MEK increases the performance of the stripper for certain applications and significantly lowers the melting point of pure DMSO. NOTE: The solvent DMSO (dimethyl sulfoxide) has a melting point just below room temperature, so it can possi¬bly freeze in storage in cooler rooms. Thawing may require several days, but afterwards the product can still be used as it is. For more details please download the info letter. Product Properties Density: 1.1 g/cm3 Melting point: 18°C Boiling point: 189°C Flash point: 87°C Vapour pressure @ 20°C: 0.56 hPa   DMSO Molecule Further Information MSDS: Safety Data Sheet DMSO (ULSI) english Sicherheitsdatenblatt DMSO (ULSI) german Specs: Specs DMSO (ULSI) Application Notes: Solvents: Theory and Application english Lösemittel: Theorie und Anwendung german Photoresist Removal english Fotolack entfernen german Further Information about Processing
TechniStrip P1316 - 5.00 l - MOS
TP1316M5
TechniStrip® P1316 High Performance Remover   General Information TechniStrip® P1316 is a remover with very strong stripping power for Novolak-based resists (including all AZ® positive resists), epoxy-based coatings, polyimides and dry films. At a typical application temperatures around 75°C TechniStrip® P1316 may dissolve cross-linked resists without residue also, e.g. through dry etching or ion implantation. The remover can also be used in spraying processes. Product Properties Flashpoint: 93°C Viscosity (20°C): < 2 cP Water Solubility: Totally miscible Boiling point: 189°C Density (at 20°C): 1.03 g/cm3 Compatibility Metals: attacked Al, Cu, Au Metals: no attack on Ta, Ni, Ti, TiN Substrates: Si, SiO2 Data on selectivity and compatibility are manufacturer information and do not claim to be complete. Please contact us for further details. Some Applications TechniStrip® P1316 is a powerful NMP-free remover for: Novolak-based positive resists such as all positive AZ® resists Epoxy-based resists Polyimides, bonding glues Dry films Further Information MSDS: Safety Data Sheet TechniStrip P1316 (MOS) english Sicherheitsdatenblatt TechniStrip P1316 (MOS) german TDS: Technical Data Sheet TechniStrip P1316 (MOS) english Specs: Specs TechniStrip P1316 (MOS) Application Notes: Photoresist Removal english Fotolack entfernen german Further Information about Processing
AZ Remover 920 - 5.00 l
1000920
AZ® Remover 920 Organic Solvent Based Remover   General Information AZ® Remover 920 is designed for fast delamination and dissolution of photoresist patterns while maintaining broad compatibility with device substrates and metal films. Merck’s proprietary solvent and additive blend is environmentally friendly and fully compliant with the European Union’s REACH regulatory code. Compatible with most AZ® positive resists (complete dissolution) and most AZ® negative resists (dissolution or delamination depending on degree of cross-linking). Product Properties Flashpoint: 84.4°C Viscosity (20°C): 1.84 cSt Boiling point: 188°C Density (at 25°C): 1.084 g/cm3 Compatibility Metals: no attack on Al, Cu, Ti, W, TiW, TiN, Sn, Ni Substrates: Si, SiO2, GaAs Data on selectivity and compatibility are manufacturer information and do not claim to be complete. Please contact us for further details. Main Features Fast delamination of photoresist patterns Broad compatibility Environmentally friendly Some Applications Bulk Photoresist Removal Metal Lift-off Lithography Cu Pillar Metallization Cleans RDL Metallization Cleans Delamination of Heavily Cured Photoresist Patterns & Organic Residues Further Information MSDS: Safety Data Sheet AZ® Remover 920 english Sicherheitsdatenblatt AZ® Remover 920 german TDS: Technical Data Sheet AZ® Remover 920 english Application Notes: Photoresist Removal english Entfernen von Fotolack german